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fety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)
Date of print: 28.12.2009
Trennex W 5000 EN
Revision date: 01.10.2009 page:1 / 4
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation: Trennex W 5000
Use of the substance / preparation:
Release agent and lubricant for pressure die casting
Name of the company:
Geiger + Co. Schmierstoff-Chemie GmbH
Postfach 1847
D 74008 Heilbronn
Phone: 0049 7131 15630 Fax: 0049 7131 156339
Department responsible for information:
Labour Email: w.mueller@trennex.de
Emergency phone: 0049 7131 15630
(buisiness hours Monday to Friday 8.00 am to 4.30 pm)
2. Hazards identification
hazard designation:
Critical hazard to man and environment:
n.a.
3. Composition/information on ingredients
chemical characterization (preparation)
description: emulsion of polysiloxanes, synthetic
hydrocarbons, emulsifiers in water
Dangerous ingredients:
EC-no.:
CAS-No.:
Identification of the hazard:
R phrases:
REACH-no.:
Classification
remark:% by
weight n.a.
Additional information
* Substance with a common (EC) occupational exposure limit value.
Full text of R-phrases: see section 16.
4. First aid measures
General information:
In all cases of doubt, or when symptoms persist, seek medical advice.
Following inhalation:
Move victim to fresh air. Put victim at rest and keep warm.
After skin contact:
After contact with skin, wash immediately with plenty of water and soap. Take off immediately all contaminated clothing.
Following eye contact:
In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart.
Remove contact lenses, if present and easy to do. Continue rinsing.
after ingestion:
If swallowed, rinse mouth with water (only if the person is conscious).
5. Fire fighting measures
Suitable extinguishing media:
alcohol resistant foam, Carbon dioxide, Powder, spray mist, (water).
Extinguishing media which must not be used for safety reasons:
Special exposure hazards arising from the substance itself, combustion products, resulting gases:
Special protective equipment for fire-fighters:
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
Date of print: 28.12.2009
Trennex W 5000 EN
Revision date: 01.10.2009 page:2 / 4
Additional information:
Do not allow water used to extinguish fire to enter drains, ground or waterways. Treat runoff as hazardous.
6. Accidental release measures
Personal precautions
Suitable eye protection.
Environmental precautions
Do not empty into drains or the aquatic environment. If the product contaminates lakes, rivers or sewages, inform competent
authorities in accordance with local regulations.
methods for cleaning up
Isolate leaked material using non-flammable absorption agent (e.g. sand, earth, vermiculit, diatomaceous earth) and collect it
for disposal in appropriate containers in accordance with the local regulations (see chapter 13).
7. Handling and storage
Handling
Information for safe handling:
When using do not eat or drink. Personal protection equipment: refer to chapter 8. Follow the legal protection and safety
regulations.
Precautions against fire and explosion:
No special measures are necessary.
Storage
Requirements for storerooms and containers:
Storage in accordance with the Ordinance on Industrial Safety and Health (BetrSiVO).
Keep container tightly closed. Store carefully closed containers upright to prevent any leaks.
Protect from heat and direct sunlight. Protect against: frost.
Information about storage in one common storage facility:
No special measures are necessary.
8. Exposure controls / Personal protection equipment
Components with workplace or biological limit values to be monitored:
EC-no.:
CAS-No.:
description: type: Value
STEL (EC) TWA (EC)unit
Additional information
Stated values are taken from the then applicable German TRGS 900 oder the German VCI table for exposure limit values.
TWA (EC): Occupational exposure limit value
STEL (EC): Short term occupational exposure limit value
Personal protection equipment
Respiratory protection:
Do not breathe gas/fumes/vapour/spray.
Hand protection:
For prolonged or repeated handling the following glove material must be used: Rubber.
Barrier creams can help protecting exposed skin areas. In no case should they be used after contact.
Eye protection:
Wear eye/face protection.
Skin protection:
No special measures are necessary.
Preventive measures:
After contact clean skin thoroughly with water and soap oder use appropriate cleanser. Wear suitable protective clothing.
9. Physical and chemical properties
Appearance:
State of matter: liquid
Paint: white
Odour: typical
Safety relevant basis data unit Method remark:
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
Date of print: 28.12.2009
Trennex W 5000 EN
Revision date: 01.10.2009 page:3 / 4
density (at temperature in °C): 20 ca.1.00 g/cm³ EN ISO 3675
Solubility in water: (g/l) complete miscible
pH (at temperature in °C): 20 7 - 9 100,0 % by weight DIN 51369
Viscosity (at temperature in °C): 20 20 s 4 mm DIN 53211
boiling temperature / boiling range: 100 °C
10. Stability and reactivity
Conditions to avoid:
Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to
chapter 7.
Materials to avoid:
Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions.
Hazardous decomposition products:
Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide,
smoke.
11. Toxicological information
Practical experience
Other observations:
Process vapours can irritate airways, skin and eyes. Has de-greasing effect on the skin.
Summarized evaluation of the CMR properties:
The components in this formulation do not meet the criteria for classification as CMR category 1 or 2.
There is no information available on the preparation itself .
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC
and classified according to the toxicological dangers.See chapters 2 and 15 for details.
12. Ecological information
Type judging:
There is no information available on the preparation itself .
This product can be eliminated from water to a large extent by abiotical procedures, e.g. adsorption to activated sludge.
Chemical Oyxgen Demand (COD): No data available.
Do not empty into drains or the aquatic environment.
Results of PBT assessment
The components in this formulation do not meet the criteria for classification as PBT or vPvB.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC
and is not classified as dangerous for the environment.
13. Disposal considerations
Appropriate disposal / Product:
Recommendation:
Do not empty into drains or the aquatic environment. Carry out a burning of harzardous waste according to official regulations.
Control report for waste code/ waste marking according to EAKV:
130105 non-chlorinated emulsions
120109 machining emulsions and solutions free of halogens
Contaminated packaging:
Recommendation:
Cleaned containers may be recycled. Vessels not properly emptied are special waste.
14. Transport information
Transport according to ADR/RID, IMDG and ICAO/IATA.
Overland transport (ADR/RID)
Class: not a dangerous good
Label: n.a.
UN No.: n.a.
Hazard identification number (Kemler No.): n.a.
Official directive for the transport:
Packing Group: n.a.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
Date of print: 28.12.2009
Trennex W 5000 EN
Revision date: 01.10.2009 page:4 / 4
Tunnel restriction code:
Transport by sea (IMDG)
Class: n.a.
Label: n.a.
IMDG-CODE-Class: n.a.
UN No.: n.a.
Official directive for the transport:
Packing Group: n.a.
Marine pollutant: n.a.
Air transport (ICAO-TI / IATA-DGR)
Class or Division:Class: n.a.
UN No.: n.a.
Packing Group: n.a.
15. Regulatory information
EU-Regulations
Chemical Safety Assessment
Chemical safety assessments for substances in this preparation were not carried out.
Classification
Danger symbol(s) and danger term(s) for dangerous materials and preparations:
Contains:n.a.
R phrases:n.a.
S phrases:n.a.
Special labelling of particular preparations:n.a.
Other regulations (EU):
biocide, active substance Required quantity
(ethylendioxy)dimethanol 3,6 g/kg
Data concerning the Directive 1999/13/EC on the limitation of emissions of volatile organic compounds (VOC-RL)
VOC-value (in g/l) , ISO 11890-2: 0
VOC-value (in g/l) , ASTM D-3960-1: 0
National regulations
Informations on working limitations:
Observe employment restrictions under the Maternity Protection Directive (EC 92/85/EEC) for expectant or nursing mothers.
Observe employment restrictions under the law for the protection of young people at work (94/33/EC).
16. Additional information
Wording of the r-phrases under paragraph 3
Further remarks:
The information supplied on this safety data sheet complies with our current level of knowledge as well as with national and
EU regulations. Without written approval, the product must not be used for purposes different from those mentioned in chapter
1. It is always the user's duty to take any necessary measures for meeting the requirements laid down by local rules and
regulations. The details in this safety data sheet describe the safety requirements of our product and are not to be regarded
as guaranteed attributes of the product.
At this time there are no sufficient data about exposure szenariosavailable.
So it´s not possible to assess the preparation